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Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II)


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Supplier:  ALADDIN SCIENTIFIC
Description:   Product classM-P, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands, M-C, Allyl Ligands, SIPr, Bidentate LigandsReaction typeCross Coupling Reactions with Arenes, Amination, Buchwald-Hartwig Aminaton, Alpha Arylation, Suzuki-Miyaura Coupling ReactionChemical propertiesChemical formulaC30H43N2ClPdEmpirical formula(SIPr)Pd(allyl)ClMolecular weight573.56MetalPdTheoretical metal content19Physical statecrystallineColoryellowMetal purity99.95Applications & referencesα-Arylation of ketones.Reference: Org. Lett. 2002, 4, 4053 (DOI: 10.1021/ol026745m); Adv. Synth. Catal. 2012, 354, 377 (DOI: 10.1002/adsc.201100669)Intramolecular arylamination step in the synthetic approach of cryptocarya alkaloids.Reference: Synlett 2003, 12, 1871 (DOI: 10.1021/jo035834p)Suzuki-Miyaura coupling reaction.Reference: J. Org. Chem. 2004, 69, 3173Buchwald-Hartwig coupling reactions.Reference: J. Am. Chem. Soc. 2006, 128, 4101 (DOI: 10.1021/ja057704z)α-Heteroarylation of ketone enolates.Reference: J. Org. Chem. 2010, 75, 5316 (DOI: 10.1021/jo100623d)Palladium catalyzed anaerobic oxidation of secondary alcohols under mild reaction conditions.Reference: J. Org. Chem. 2011, 76, 1390. (DOI: 10.1021/jo102385u)Palladium catalyzed Buchwald-Hartwig- Reaction at room temperature.Reference: J. Am. Chem. Soc. 2006, 128, 4101. (DOI: 10.10217ja057704z)
New Product
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Supplier:  AMBEED, INC
Description:   Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II) 98%
New Product
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Supplier:  Strem Chemicals Inc
Description:   NHC
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Stock for this item is limited, but may be available in a warehouse close to you. Please make sure that you are logged in to the site so that available stock can be displayed. If the call is still displayed and you need assistance, please call us at 1-800-932-5000.
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